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81.
82.
Quartz veins are developed in a wide range of metasediment types in the upper amphibolite facies rocks of Connemara, and attest to considerable migration of silica. Contrary to common assumptions, there is clear evidence that these veins do not primarily result from movement of fluid to regions of lower P–T down the regional geothermal gradient. Under amphibolite facies conditions, a dilute chloride fluid moving down temperature has the potential to alter 60g of plagioclase to muscovite for each gram of vein quartz precipitated, while cooling over the temperature interval from 650 to 500° C. The absence of significant metasomatic effects in the vein walls effectively precludes a simple origin from such through-flowing, externally derived fluids. The oxygen isotopic composition of matrix quartz shows considerable differences between different rock types (quartzite, pelite and marble), with a range of δ18OSMOW from c.+ 11.5% (quartzite) to + 18.5% (marble). In each rock type, vein quartz compositions closely match those of the matrix quartz. These results demonstrate the importance of local segregation processes in the formation of veins, and suggest that fluid convection cells were not developed during metamorphism on a scale larger than the individual sedimentary formations, if at all. Both oxygen isotope data and the absence of metasomatism indicate that veins form primarily by segregation of quartz from the host lithologies, with only a relatively minor component of through flow of externally derived fluid. Veins are clearly not the major pathways of metamorphic dewatering. It is proposed that abundant veins in the predominantly pelitic Ballynakill Formation formed during peak metamorphic D3 folding because the formation was embrittled by high fluid pressures but was capped by impermeable marble. Hence the pelitic formation fractured repeatedly and the pore fluid drained through the fractures to form veins, while irreversible loss through the rest of the succession was a much less important process. In the central mountains of Connemara, rather pure, unreactive quartzites are cut by widely spaced, laterally extensive quartz veins that are axial planar to D3 folds. These veins may mark pathways whereby metamorphic fluid made its way through the massive impermeable quartzite from lower parts of the nappe pile, but here too, oxygen isotope data indicate considerable segregation of locally derived quartz, reflecting the importance of pumping of fluid between wail rocks and fractures relative to the component of through flow.  相似文献   
83.
A systematic study of the lipid composition of thirteen bacterial species and three Recent sediments (methanogenic sediment, cyanobacterial mat and evaporative gypsum crust) was undertaken in an attempt to recognize bacterial organic matter in sediments. A sequential method, which distinguishes between three different modes of occurrence of lipid moieties (free, OH- and H+-labile), was applied. The acid-labile fractions are discussed.The three main groups of bacteria, archaebacteria, gram-positive eubacteria and gram-negative eubacteria, are easily distinguished. Methanogenic and extremely halophilic archaebacteria are characterized by the presence of diphytanyl glyceryl ether and the absence of fatty acids. The gram-positive eubacteria contain primarily iso- and anteiso-branched fatty acids whereas the gram-negative bacteria and sediments are dominated by β- and α-hydroxy fatty acids. A wide variety of H+-labile hydroxy fatty acids was observed which included several, as yet unknown, structures.β-Hydroxy fatty acids in this H+-labile mode of occurrence are exclusively present in bacteria. Their distribution patterns in sediments are considered “fingerprints” of past and present bacterial populations. The specific differences in β -hydroxy fatty acid compositions observed in the different bacteria and the three sediments investigated, suggest that amide-linked β-hydroxy fatty acid patterns are useful as markers of bacterial populations and therefore of environmental conditions.  相似文献   
84.
东昆仑西段祁漫塔格群的重新厘定   总被引:5,自引:0,他引:5  
通过区域地质调查和研究,认为前人所建立的的祁漫塔格群或滩间山群包括了不同时代的浅变质碎屑岩、中酸性火山岩及基性-超基性岩。根据在东昆仑原划奥陶系祁漫塔格群第一亚群(下部碎屑浊积岩)中采集到早志留世笔石化石组合(这是首次证实东昆仑地区存在志留系地层)及同位素测年资料(鸭子大板火山岩年龄),其时代包含了奥陶纪、志留纪和三叠纪等,根据中国地层指南及中国地层指南说明书和地层清理,对祁漫塔格群进行了解体,将其重新厘定为奥陶纪滩间山群(OT)、志留纪白干湖岩组(Sb)弧后盆地复理石沉积和鸭子泉组(Sy)岛弧火山岩、石炭纪鸭子大坂硅质岩(S i)、三叠纪鄂拉山组(T3e)、蓟县纪狼牙山岩组(Jx l)和南华—奥陶纪阿牙克库木湖蛇绿混杂岩[(N h—O)aΣ]。该成果对于祁漫塔格地区早古生代地层划分对比、构造演化提供了重要新证据。  相似文献   
85.
极谱法同时测定岩石中的微量铀钍   总被引:2,自引:0,他引:2  
试样经过氧化钠熔融后,用硝酸溶液提取熔块,加入十六烷基三甲基溴化铵(CTMAB)凝聚硅胶,过滤除硅,TBP萃淋树脂分离富集铀钍。在含0.02g/L四丁基碘化铵-4g/L铜铁试剂、pH=5的乙酸-乙酸钠极谱测定体系中同时测定铀钍,铀钍的线性范围为0.001~0.500μg/10mL。本法用于含铀岩石中微量铀钍的同时测定,结果令人满意。  相似文献   
86.
以颗粒状和粉末状膨润土防水毯(GCLs)为对象,运用GDS (global digital systems)全自动渗透仪开展渗透试验,研究CaCl_2溶液作用下GCLs渗透性能的温度效应,初步探讨其机理。试验表明:当水化液为0.05mol/L的CaCl_2溶液时,两种GCLs渗透系数随温度升高呈现增大趋势;当水化液为去离子水时,颗粒状GCL渗透系数随温度升高而减小,粉末状GCL渗透系数随温度升高而增大。去离子水情况下,膨润土吸附结合水量随温度升高而减小;CaCl_2溶液作用下,吸附结合水量较去离子水情况大幅降低。当CaCl_2溶液浓度一定时,膨润土膨胀指数随温度升高而略有增大;当温度一定时,膨润土膨胀指数随CaCl_2溶液浓度升高而显著减小。以去离子水进行试验时:颗粒状和粉末状GCLs渗透系数随温度的变化主要影响因素为凝胶态蒙脱石数量,其次为流体黏滞系数和吸附结合水量;颗粒状GCLs膨润土孔隙结构越不均匀,凝胶态蒙脱石数量的影响就越显著,导致渗透系数随温度升高而减小、固有渗透率随温度升高显著降低。以CaCl_2溶液进行试验时,两种GCLs渗透系数随温度变化的主要受流体黏滞系数和吸附结合水量的影响,而受凝胶态蒙脱石数量的影响较小。孔隙溶液性质、温度和膨润土类型均对GCLs的防渗性能具有重要影响。  相似文献   
87.
渤海表层沉积物中的生物硅   总被引:1,自引:0,他引:1  
采用0.1 mol/L HCl和1%Na2CO3两步连续提取法,对103个渤海表层沉积物样品的生物硅含量进行了分析,结果表明,渤海表层沉积物中生物硅含量范围为7.3~54.7 g/kg,均值31.5 g/kg,高于其他相关调查,原因可能是由于采用0.1 mol/L HCl提取过程中,破坏了生物硅表面的金属氧化膜。对沉积物生物硅含量的空间分布表征显示,莱州湾是沉积物生物硅的低值区、而渤海湾与辽东湾之间的河北沿岸海域是相对高值区,初步认为是陆源营养物质的输入与黄河泥沙长期不断输入干扰沉积环境的稳定性,造成了该海域表层沉积物生物硅分布差异。主成分分析显示,生物硅含量与沉积物黏粒含量、细粉砂、有机氮、有机碳的含量均呈极显著正相关(P0.01),进一步证实沉积物粒度特征和营养环境对生物硅积累的影响。  相似文献   
88.
In the present research, effect of silica fume as an additive and oil polluted sands as aggregates on compressive strength of concrete were investigated experimentally. The amount of oil in the designed mixtures was assumed to be constant and equal to 2% of the sand weight. Silica fume accounting for 10%, 15% and 20% of the weight is added to the designed mixture. After preparation and curing, concrete specimens were placed into the three different conditions: fresh, brackish and saltwater environments (submerged in fresh water, alternation of exposed in air & submerged in sea water and submerged in sea water). The result of compressive strength tests shows that the compressive strength of the specimens consisting of silica fume increases significantly in comparison with the control specimens in all three environments. The compressive strength of the concrete with 15% silica fume content was about 30% to 50% higher than that of control specimens in all tested environments under the condition of using polluted aggregates in the designed mixture.  相似文献   
89.
以2011年6月和8月在长江口邻近海域采集的沉积物和间隙水样品为研究对象,讨论了沉积物中生物硅(BSi)和间隙水中溶解硅(DSi)的分布情况和影响因素,并初步探讨了生物硅的循环和保存。结果表明,表层沉积物中BSi的含量较低,且均小于1%。柱状沉积物中BSi的含量范围为0.34%~0.52%。C3、D1站位柱状沉积物中BSi的记录主要是由早期成岩过程控制,33#站位的分布特征主要是由水动力等变化控制。沉积物间隙水中DSi的浓度范围为101.6~263.9 μmol/L,低于纯BSi的溶解度;间隙水的pH值越大,沉积物的含水率越低,还原性越强,间隙水中DSi的含量越高。3站位生物硅的埋藏效率均较高,表明长江口邻近海域是潜在的硅的汇。沉积通量的分布与沉积速率和埋藏效率的分布一致,均有近岸高于远海的趋势。  相似文献   
90.
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